Every time I try to call an international number from Australia it says " the number you have called is not available from this service". I am mainly trying to call the Philippines.
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You may have call barring for international calls
Is your mobile phone on a Pre-Paid offer or Post Paid plan?
If it's a Pre-Paid, what plan is it?
Some plans use "extra credit" for International Calls. If your "extra credit" has been used, then a top up recharge is needed to make International Calls to some countries.